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Aminopyridine functionalized cellulose based Pd nanoparticles: An efficient and ecofriendly catalyst for the Suzukicross-coupling reaction

Peibo Hu,Yahao Dong,Xiaotian Wu,Yuping Wei

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 3,   Pages 389-395 doi: 10.1007/s11705-016-1575-1

Abstract: This catalyst can be applied in the Suzuki cross-coupling reaction of aryl halides with arylboronic acids

Keywords: cellulose-supported     2-aminopyridine     palladium nanoparticles     ecofriendly catalyst     Suzuki cross-coupling    

Pd/Fe3O4 supported on bio-waste derived cellulosic-carbon as a nanocatalyst for C–C coupling and electrocatalytic

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 10,   Pages 1514-1525 doi: 10.1007/s11705-022-2158-y

Abstract: O4@C magnetic nanocatalyst demonstrated excellent catalytic activity in the Hiyama cross-couplingexcellent catalytic activity up to five recycles without significant catalytic activity loss in the Hiyama cross-coupling

Keywords: bio-waste     cellulosic-carbon     Pd/Fe3O4     Hiyama cross-coupling     hydrogen evolution    

Pd-Ni nanoparticles supported on titanium oxide as effective catalysts for Suzuki-Miyaura coupling reactions

Dongxu Han, Zhiguo Zhang, Zongbi Bao, Huabin Xing, Qilong Ren

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 24-31 doi: 10.1007/s11705-017-1669-4

Abstract: prepared Pd-Ni/TiO exhibited enhanced catalytic activity compared to an equal amount of Pd/TiO for Suzuki-Miyaura

Keywords: Pd-Ni bimetallic nanoparticles     nanocatalysis     Suzuki-Miyaura reaction     titanium oxide    

Mild and highly regioselective synthesis of biaryl acids via Rh(I)-catalyzed cross-dehydrogenative coupling

Yun Liu, Youquan Zhu, Chaojun Li

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 3-8 doi: 10.1007/s11705-017-1693-4

Abstract: A mild and efficient synthesis for the biaryl acids via rhodium-catalyzed cross-dehydrogenative coupling

Keywords: biaryl acids     cross-dehydrogenative coupling     rhodium-catalyzed    

Chord error constraint based integrated control strategy for contour error compensation

Tie ZHANG, Caicheng WU, Yanbiao ZOU

Frontiers of Mechanical Engineering 2020, Volume 15, Issue 4,   Pages 645-658 doi: 10.1007/s11465-020-0601-7

Abstract: As the traditional cross-coupling control method cannot meet the requirements for tracking accuracy andcontour control accuracy in large curvature positions, an integrated control strategy of cross-couplingcontour error compensation based on chord error constraint, which consists of a cross-coupling controllerTo reduce the contour error, a PI-type cross-coupling controller is designed, with its stability being

Keywords: cross-coupling controller     contour error     tracking error     position error compensator     feed rate regulator    

Development of highly active coated monolith SCR catalyst with strong abrasion resistance for low-temperature application

Lina GAN,Shan LEI,Jian YU,Hongtao MA,Yo YAMAMOTO,Yoshizo SUZUKI,Guangwen XU,Zhanguo ZHANG

Frontiers of Environmental Science & Engineering 2015, Volume 9, Issue 6,   Pages 979-987 doi: 10.1007/s11783-015-0824-8

Abstract: Monolith SCR catalysts coated with V O -WO /TiO were prepared by varying binder and coating thickness. Comparing with a monolith extruded with 100% V O -WO /TiO powder, a coated monolith with a catalyst-coating layer of 260 μm in thickness exhibited the similar initial NO reduction activity at 250°C. After 4 h abrasion (attrition) in an air stream containing 300 g·m fine sands (50–100 μm) at a superficial gas velocity of 10 m·s , the catalyst still has the activity as a 100% molded monolith does in a 24-h activity test and it retains about 92% of its initial activity at 250°C. Estimation of the equivalent durable hours at a fly ash concentration of 1.0 g·m in flue gas and a gas velocity of 5 m·s demonstrated that this coated monolith catalyst is capable of resisting abrasion for 13 months without losing more than 8% of its initial activity. The result suggests the great potential of the coated monolith for application to de-NO of flue gases with low fly ash concentrations from, such as glass and ceramics manufacturing processes.

Keywords: coated monolith     low-temperature denitration     abrasion resistance     attrition    

Evaluation method of dam behavior during construction and reservoir filling and application to real dams

Yuji KOHGO, Akira TAKAHASHI, Tomokazu SUZUKI,

Frontiers of Structural and Civil Engineering 2010, Volume 4, Issue 1,   Pages 92-101 doi: 10.1007/s11709-010-0009-2

Abstract: In this paper we analyzed a real fill-type dam, named the Minami-Aiki Dam, to verify a numerical consolidation method with an elastoplastic model for unsaturated soils. The validities were conducted by comparing the analyzed and measured values during construction and impounding. The settlements calculated showed good agreement to those observed. Though the changing patterns of the measured and calculated pore water pressures were similar, the amounts of pore water pressures induced by the self-weights of embankment and the dissipation speeds were different. The earth pressures measured at the bottom of the core zone showed good agreement with those calculated. This method is valid for estimating behavior of fill-type dams during construction and impounding.

Keywords: fill dam     consolidation analysis     unsaturated geo-materials     impounding     construction    

Simultaneous removal of trihalomethanes by bimetallic Ag/Zn: kinetics study

Ahmed H A DABWAN, Satoshi KANECO, Hideyuki KATSUMATA, Kiyoyuki EGUSA, Tohru SUZUKI, Kiyohisa OHTA,

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 3,   Pages 322-327 doi: 10.1007/s11705-009-0261-y

Abstract: In the present work, bimetallic silver/zinc was applied into the degradation of trihalomethanes, THMs: CHCl, CHBrCl, CHBrCl, and CHBr. The kinetics reaction rates and removal efficiencies of the THM compound mixtures, in the aqueous solutions, were investigated. Batch experiments were conducted under mild conditions, ambient temperature, and pressure. The primary degradation reaction followed a pseudo-first-order kinetic law. The first-order rate constants and the degradation efficiencies followed the decreasing order of CHBr>CHBrCl>CHBrCl>CHCl. The bond dissociation energy and hydrophilic/hydrophobic characteristics of the THM compounds may become the most important parameters affecting the degradation kinetics and efficiency by bimetallic Ag/Zn.

Keywords: reaction     first-order     dissociation     degradation reaction     aqueous    

Enhanced hydrogen production from aqueous methanol solution using TiO

Paramasivan GOMATHISANKAR,Tomoko NODA,Hideyuki KATSUMATA,Tohru SUZUKI,Satoshi KANECO

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 2,   Pages 197-202 doi: 10.1007/s11705-014-1417-y

Abstract: The photocatalytic hydrogen production from aqueous methanol solution using titanium dioxide (TiO ) was investigated in the addition of metal particles including copper, lead, tin, and zinc. The results show that only the addition of copper particles enhances the hydrogen production. The copper usage and reaction temperature were further optimized for TiO /Cu photocatalyts. Under the optimal conditions, the hydrogen production using TiO /Cu as photocatalysts is approximately 68 times higher than that obtained with only TiO .

Keywords: photocatalytic hydrogen generation     methanol     copper particles     TiO2     metal-semiconductor interface    

Microdamage study of granite under thermomechanical coupling based on the particle flow code

Frontiers of Structural and Civil Engineering   Pages 1413-1427 doi: 10.1007/s11709-023-0953-2

Abstract: The thermomechanical coupling of rocks refers to the interaction between the mechanical and thermodynamicThe study of this coupling interaction is essential for understanding the mechanical and thermodynamicA series of numerical thermomechanical coupling tests are then conducted to calibrate the micro-parameters

Keywords: thermomechanical coupling effect     granite     improved linear parallel bond model     thermal property     particle    

Simulation of steel beam under ceiling jet based on a wind–fire–structure coupling model

Frontiers of Structural and Civil Engineering 2023, Volume 17, Issue 1,   Pages 78-98 doi: 10.1007/s11709-022-0936-8

Abstract: Instead of applying the concept of adiabatic surface temperature (AST) to achieve fluid–structure coupling

Keywords: CFD–FEM coupling     steel beam     wind     ceiling jet     numerical heat transfer    

catalysts derived from zeolitic imidazolate framework@MXene composites for efficient oxidative self-coupling

Frontiers of Chemical Science and Engineering 2023, Volume 18, Issue 1, doi: 10.1007/s11705-023-2378-9

Abstract: The catalytic efficiency of the catalyst is tested for the self-coupling of 4-methoxybenzylamine to produce

Keywords: MXene     sacrificial template     oxidative self-coupling     Co nanoparticles     imine    

Determination of aniline derivatives in water samples after preconcentration with oxidized multiwalled carbon nanotubes as solid-phase extraction disk

Hideyuki KATSUMATA, Yuta ODA, Satoshi KANECO, Tohru SUZUKI, Kiyohisa OHTA

Frontiers of Chemical Science and Engineering 2012, Volume 6, Issue 3,   Pages 270-275 doi: 10.1007/s11705-012-1298-x

Abstract: A sensitive and selective preconcentration method using solid-phase extraction (SPE) disk made from oxidized multiwalled carbon nanotubes (OMWCNTs), has been developed for the determination of aniline derivatives, such as 2-nitroaniline (2-NA), 4-nitroaniline (4-NA), and 2,4-dichloroaniline (2,4-DCA) in water samples. Anilines were extracted onto OMWCNT disk and then determined by high performance liquid chromatography (HPLC) with UV detector. Several parameters on the recovery of the analytes were investigated. The experimental results showed that it was possible to obtain quantitative analysis when the solution pH was 8 using 200 mL of validation solution containing 2 μg of anilines and 10 mL of acetonitrile/ethanol (8/2, v/v) as an eluent. Relative standard deviations for five determinations were 7.5% (2-NA), 6.5% (4-NA) and 3.8% (2,4-DCA) under optimum conditions. The linear range of calibration curves were 0.5 ng·mL to 15 ng·mL for each analyte with good correlation coefficients. The detection limits (3S/N) of 2-NA, 4-NA and 2,4-DCA were 30 pg·mL , 31 pg·mL and 26 pg·mL , respectively. Our method was successfully applied to the determination of aniline compounds in river water sample with high precision and accuracy.

Keywords: aniline determination     solid-phase extraction     oxidized multiwalled carbon nanotubes     water sample     HPLC-UV    

Effect of alkyl nitrite decomposition on catalytic performance of CO coupling reaction over supported

Zhenhua LI, Weihan WANG, Dongxue YIN, Jing LV, Xinbin MA

Frontiers of Chemical Science and Engineering 2012, Volume 6, Issue 4,   Pages 410-414 doi: 10.1007/s11705-012-1213-5

Abstract: The syntheses of dimethyl oxalate (DMO) and diethyl oxalate (DEO) by CO coupling reaction in gaseous

Keywords: palladium     CO coupling     dialkyl oxalate     alkyl nitrite     decomposition    

Thermodynamic and economic analyses of a coal and biomass indirect coupling power generation system

Buqing YE, Rui ZHANG, Jin CAO, Bingquan SHI, Xun ZHOU, Dong LIU

Frontiers in Energy 2020, Volume 14, Issue 3,   Pages 590-606 doi: 10.1007/s11708-020-0809-6

Abstract: The coal and biomass coupling power generation technology is considered as a promising technology forIn this paper, a novel coal and biomass indirect coupling system is proposed based on the technologyFor the sake of comparison, a coal and biomass direct coupling system is also introduced based on theThe process of the direct and the indirect coupling system is simulated.worse, but the economic performance is better than that of the direct coupling system.

Keywords: biomass     indirect coupling system     process simulation     thermodynamic analysis     economic analysis    

Title Author Date Type Operation

Aminopyridine functionalized cellulose based Pd nanoparticles: An efficient and ecofriendly catalyst for the Suzukicross-coupling reaction

Peibo Hu,Yahao Dong,Xiaotian Wu,Yuping Wei

Journal Article

Pd/Fe3O4 supported on bio-waste derived cellulosic-carbon as a nanocatalyst for C–C coupling and electrocatalytic

Journal Article

Pd-Ni nanoparticles supported on titanium oxide as effective catalysts for Suzuki-Miyaura coupling reactions

Dongxu Han, Zhiguo Zhang, Zongbi Bao, Huabin Xing, Qilong Ren

Journal Article

Mild and highly regioselective synthesis of biaryl acids via Rh(I)-catalyzed cross-dehydrogenative coupling

Yun Liu, Youquan Zhu, Chaojun Li

Journal Article

Chord error constraint based integrated control strategy for contour error compensation

Tie ZHANG, Caicheng WU, Yanbiao ZOU

Journal Article

Development of highly active coated monolith SCR catalyst with strong abrasion resistance for low-temperature application

Lina GAN,Shan LEI,Jian YU,Hongtao MA,Yo YAMAMOTO,Yoshizo SUZUKI,Guangwen XU,Zhanguo ZHANG

Journal Article

Evaluation method of dam behavior during construction and reservoir filling and application to real dams

Yuji KOHGO, Akira TAKAHASHI, Tomokazu SUZUKI,

Journal Article

Simultaneous removal of trihalomethanes by bimetallic Ag/Zn: kinetics study

Ahmed H A DABWAN, Satoshi KANECO, Hideyuki KATSUMATA, Kiyoyuki EGUSA, Tohru SUZUKI, Kiyohisa OHTA,

Journal Article

Enhanced hydrogen production from aqueous methanol solution using TiO

Paramasivan GOMATHISANKAR,Tomoko NODA,Hideyuki KATSUMATA,Tohru SUZUKI,Satoshi KANECO

Journal Article

Microdamage study of granite under thermomechanical coupling based on the particle flow code

Journal Article

Simulation of steel beam under ceiling jet based on a wind–fire–structure coupling model

Journal Article

catalysts derived from zeolitic imidazolate framework@MXene composites for efficient oxidative self-coupling

Journal Article

Determination of aniline derivatives in water samples after preconcentration with oxidized multiwalled carbon nanotubes as solid-phase extraction disk

Hideyuki KATSUMATA, Yuta ODA, Satoshi KANECO, Tohru SUZUKI, Kiyohisa OHTA

Journal Article

Effect of alkyl nitrite decomposition on catalytic performance of CO coupling reaction over supported

Zhenhua LI, Weihan WANG, Dongxue YIN, Jing LV, Xinbin MA

Journal Article

Thermodynamic and economic analyses of a coal and biomass indirect coupling power generation system

Buqing YE, Rui ZHANG, Jin CAO, Bingquan SHI, Xun ZHOU, Dong LIU

Journal Article